Tuesday, 16 September 2014
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Copper nanowires show promise in energy conversion

Researchers at Duke University in the US are using copper to transform sunlight and water into a chemical fuel.

Converting solar energy into storable fuel remains a challenge. One of the ways chemists have tried to capture the power of the sun is through water splitting, in which the atoms of H2O are broken apart so the hydrogen may be collected and used as fuel.

Plants do this through photosynthesis, and for half a century, scientists have tried to recreate that process by tinkering with chemical catalysts jumpstarted by sunlight.

Indium tin oxide (ITO) is one material they’ve commonly tried to use as its transparency allows sunlight to pass through and trigger the water-splitting reactions. ITO also conducts electricity but it is far from being an ideal material.

‘Indium is not very abundant,’ said Ben Wiley, assistant professor of chemistry at Duke University. ‘It is similar in abundance to silver in the earth’s crust.’

Consequently, solar fuel cells using ITO will likely remain expensive and uncompetitive with conventional energy sources like coal and natural gas, he said in a statement.

Wiley’s lab has created copper nanowires fused in a transparent film in a bid to replace ITO. The team — including two postdoctoral researchers, a graduate student, and a former graduate student from Duke — published their new approach last month in the Angewandte Chemie.

Copper is 1,000 times more plentiful and 100 times less expensive than indium. Copper nanowire catalysts also cost less to produce than their ITO counterparts because they can be ‘printed’ on pieces of glass or plastic in a liquid ink form, using a machine that functions much like a printing press. ITO production, by contrast, requires large, sequential chambers of pumps and vacuums that deposit a thin layer of indium atoms at a far slower rate.

The copper nanowire films consist of networks of microscopic metal rods, the properties and applications of which Wiley’s lab has studied for years.

The nanowires provide a high surface area for catalysing chemistry, and Wiley’s team experimented with coating them in either cobalt or nickel, which are the metals that serve as the actual chemical catalyst.

Even with a coat of cobalt or nickel, the nanowire films allow nearly seven times more sunlight to pass through than ITO. The films are also flexible, leading Wiley to imagine the completed fuel cells one day being attached to backpacks or cars.

In the interim, engineering and chemistry challenges remain. The nanowire films carry out only one half of the water-splitting equation, a process called water oxidation. The other half of the reaction involves using the electrons obtained from water oxidation to reduce water to hydrogen. Wiley’s team expects to publish their work on this process in the coming year.

He said: ‘A lot of groups are working on putting together complete devices to generate fuels from sunlight…the efficiencies and costs of these systems have to be improved for them to get to commercial [production].’

Wiley noted that solar energy production is just one application of the copper nanowire films they study. The nanowires also show promise for use in flexible touch screens, organic LED (or OLED) lights and smart glass.


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