Wednesday, 26 November 2014
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Nanobeads could store liquid hydrogen to fuel cars

Plastic nanobeads that can store hydrogen at room temperature as a liquid are being commercialised for fuel applications by technology start-up Cella Energy.

It follows around five years of research into storable hydrogen fuels led by Prof Stephen Bennington at Rutherford Appleton Laboratory in Oxford and the London Centre for Nanotechnology at University College London.

One of the major stumbling blocks for hydrogen-powered vehicles is figuring out a way to carry enough hydrogen on board to travel even moderate distances between refuelling stops.

Currently, storing hydrogen requires either high-pressure cylinders at up to 700 times atmospheric pressure or super cooling to a liquid at -253oC.

Hydrides, which are powdered solids made up of hydrogen bonded to a more electropositive element or group, have been touted as one solution. In 2005 the US Department of Energy announced it would be investing $64m (£40.4m) to fund research into hydrides and other hydrogen storage technologies.

However, as Bennington pointed out, hydrides are not quite ready.

‘When you heat them up they take several hours for the hydrogen to come out — that’s obviously not ideal for fuel. Second, they’re either very sensitive to oxygen in the sense that they degrade very quickly in air, or they’re high flammable.’

Bennington and his team devised a way of attaching the hydrides to nanoscale polymer fibres through a process called electrospinning. In this form the hydrides are safer, have a longer life and the hydrogen is released almost instantaneously upon heating.

‘You extrude the polymer and the hydride in a solution and put a large electric field on it and out the bottom of that comes these nanofibres — we think that’s a scalable process,’ Bennington said.

The group then began investigating nanobeads rather than fibres, which have the added advantage that they can be poured and pumped like a liquid.

‘The idea would be that you have two nozzles. When you go to fuel your car one nozzle will be giving you the fresh polymer beads with hydride and the other one is sucking out the used stuff, which is then sent off to be recycled — that’s our vision.’

Specialist chemical company Thomas Swan and Co is providing investment for initial demonstrations of the technology.

In tandem with the automotive application, Cella Energy is also looking at portable fuel cells for military personnel. Currently, soldiers carry lithium-ion batteries to power high-tech kit such as night-vision headsets. Bennington thinks a portable hydrogen bag incorporating their polymer fibres could provide a lighter and more efficient solution.


Readers' comments (4)

  • One wonders what is currently the amount of hydrogen storable per Kg or Ltr of nanobeads.

    Also, could this technology be used for CO2 storage in power stations?

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  • With all due respect to Stephen Bennington, essentially the same technique was worked out several years ago by a team led by George Wicks at the U.S.'s Savannah River National Lab. Wicks' group used porous glass microbeads to hold the hydrogen. The advantage of the microbeads is that they are reusable and can be produced by the ton (electrospraying and electrospinning, as yet, can't meet that production level. For more information and these glass beads, see the stories published by The American Ceramic Society at http://americanceramicsociety.org/bulletin/jun_08/#/25/

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  • Interesting stuff! Thanks to Peter Wray for the link too.

    I've posted a link to this story on the wall of the www.facebook.com/poweringnow page (the facebook home to the Canadian Hydrogen and Fuel Cell Association).

    They actually have a show called HFC2011 about Hydrogen Fuel Cells in Vancouver in May this year - www.hfc2011.com which may interest some of your readers.



    Nikki Sheppard
    Manchester (UK)

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  • The article is OK. But when comes to electrospinning and attaching plastic fibres to it is heavy stuff, which definitely needs financial consideration. Morover, propoerties of hydrites are subjected to temperature and vacuum which could result in loss of hydrogen while refilling..

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