Princeton team make hydrogen from wastewater

Researchers have harnessed sunlight to isolate hydrogen from industrial wastewater, an advance that could lead to a less energy intensive and cheaper method of producing pure hydrogen.

wastewater
Professor Zhiyong Jason Ren and Lu Lu, associate research scholar at the Andlinger Center for Energy and the Environment (Pic: Bumper DeJesus, Andlinger Center for Energy and the Environment)

In a paper in Energy & Environmental Science, the researchers at Princeton University reported that their process doubled the currently accepted rate for scalable technologies that produce hydrogen by splitting water.

The technique is said to use a specially designed chamber with a black silicon interface to split water and isolate hydrogen gas. The process is aided by bacteria that generate electrical current when consuming organic matter in the wastewater; the current, in turn, aids the water splitting process.

The team, led by Zhiyong Jason Ren, professor of civil and environmental engineering and the Andlinger Center for Energy and the Environment at Princeton, chose wastewater from breweries for the test. They ran the wastewater through the chamber, used a lamp to simulate sunlight, and watched the organic compounds breakdown and the hydrogen bubble up.

In a statement, the researchers said the technology could appeal to refineries and chemical plants, which typically produce their own hydrogen from fossil fuels, and face high costs for cleaning wastewater.

Historically, hydrogen production has relied on oil, gas or coal, and an energy-intensive method that involves processing the hydrocarbon stock with steam. Chemical manufacturers then combine the hydrogen gas with carbon or nitrogen to create high-value chemicals, such as methanol and ammonia.

The chemical industry is currently the largest producer and consumer of hydrogen. Producing chemicals in highly industrialised countries requires more energy than producing iron, steel, metals and food, according to a 2016 report from the US Energy Information Administration. The report estimates that producing basic chemicals will continue to be the top industrial consumer of energy over the next two decades.

“It’s a win-win situation for chemical and other industries,” said Lu Lu, the first author on the study and an associate research scholar at the Andlinger Center. “They can save on wastewater treatment and save on their energy use through this hydrogen-creation process.”

According to the researchers, this is the first time that wastewater, not lab-made solutions, has been used to produce hydrogen using photocatalysis. The team produced the gas continuously over four days until the wastewater ran out, which is significant, the researchers said, because comparable systems that produce chemicals from water have failed after a couple hours of use.

The researchers measured the hydrogen production by monitoring the amount of electrons produced by the bacteria, which directly correlates to the amount of hydrogen produced. The measurement was at the high end for similar lab experiments and, Ren said, twice as high as technologies with the potential to scale for industrial use.

Ren said he sees this technology as scalable because the chamber used to isolate the hydrogen is modular, and several can be stacked to process more wastewater and produce more hydrogen.

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