A new analytical technique that uses infrared spectroscopy to study light-sensitive organic materials could lead to the development of cheaper, more efficient solar cells.
Using infrared (IR) spectroscopy to study the vibrations of atoms within the material, the technique provides information about the movement of electrons within a film of carbon-based materials.
Obtaining this information is a critical step in the development of a new class of solar cells, which promise significant savings in production costs compared to conventional silicon-based cells. The new analytical technique was developed by a team led by
Organic photovoltaic (OPV) devices have become important because they are much less expensive to produce than silicon-based solar cells. The material consists of a film made of two different types of chemicals: a polymer that releases an electron when it is struck by a photon of light and a large molecule that accepts the freed electrons. This molecule is based on the football-shaped ‘buckminsterfullerene’ carbon molecules popularly known as ‘buckyballs.’
Because the electrical interactions needed to produce an electric current occur at the interfaces of the two components of this polymer blend, materials scientists need to understand the arrangement of molecules in the film. Asbury’s new analytical technique provides a closer look at this arrangement than techniques used traditionally.
Previous studies, using atomic-force microscopy, supply general information about the packing of the molecules, but they provide very limited information about the interfaces where the molecules actually come together. IR spectroscopy, on the other hand, provides a more detailed picture of the interface by tracing the exchange of electrons between two molecules of the film.
‘The problems with OPVs today are that they are not efficient enough and they tend to stop working over time,’ said Asbury. In order to develop a useful electric current, the flow between the two components must be optimised. ‘To improve performance, we need to understand what happens at the molecular level when light is converted to electrons,’ Asbury explained.
When the film is exposed to light, each photon excites an electron in the polymer. If an interface between the polymer molecule and the functionalised buckminsterfullerene exists, a current can be produced. However, in the materials developed to date, many of the electrons appear to become sidetracked. Asbury exposes the film to light using ultrashort laser pulses, which causes photons of light to be converted to electrons across the entire surface at the same time. Two-dimensional IR spectroscopy is used to monitor the vibration of the molecules within the film.
‘The vibrations of the molecules are strongly affected by the presence or absence of electrons,’ said Asbury. ‘We use these vibrations as a probe to track the movement of electrons. By varying the structures of the materials, we expect to identify the side paths that reduce efficiency and ultimately to use that information to guide material design.’ The ultimate goal is a solar cell that is sufficiently inexpensive and efficient that it can be used on a rooftop to provide the electrical energy needed in a building.
Mandatory Renewable Energy – The Energy Evolution
Our [the USA’s] dependence on fossil fuels could lead to catastrophic consequences.
Federal, state and local government should implement a mandatory renewable energy installation for residential and commercial property on new construction and remodelling, with the use of energy efficient material, mechanical systems, appliances, and lighting etc.
The source of energy must be renewable energy, such as solar-photovoltaic, geothermal, wind, and biofuels etc.
The implementation could be done on a gradual scale over the next 10 years. At the end of the 10 year period all construction and energy use in the structures throughout the United States must be 100% powered by renewable energy.
In addition the government must impose laws, rules and regulations, whereby the utility companies must comply with a fair “NET METERING” (the buying of excess generation from the consumer). Similarly, the government should promote the research and production of renewable energy technology with various long term incentives and grants. Utilise various foundations to contribute to this cause. Utilise water from lakes, rivers and oceans to circulate in cooling towers to produce air conditioning. Utilise proper landscaping to reduce energy consumption.
We should also include a mandatory time table for the automobile industry to gradually produce an automobile powered by renewable energy. The American automobile industry is surely capable of accomplishing this task.
This is a way to expedite our energy independence and economic growth.
It will take a maximum effort of the private, commercial, industrial and government sectors commitments to renewal energy, in order to achieve our energy independence.