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In a recent issue of the American Chemical Society journal Langmuir, Rutgers scientists and collaborators from Ceramare Corporation and the
The resulting orderly array of particles mimics the performance of traditionally fabricated crystalline wafers, without the time and expense of growing crystals in a molten mixture or solution, then slicing them into thin layers.
“The materials we’ve created in our lab bridge the gap between single-crystal materials, with their precisely ordered atomic structures, and ceramics, which have randomly oriented structures,” said Richard Riman, professor of ceramic and materials engineering. “These so-called ‘single-crystal-like’ materials possess properties approaching those of true single crystal materials, but since we make them with techniques drawn from ceramic fabrication, there is potential to synthesise them economically and in large size and quantity.”
Riman and his colleagues conducted their research with lead zirconate titanate (PZT), which is used in motion sensors, electrical capacitors and even for vibration damping in high-performance skis and tennis racquets. PZT has proven almost impossible to fabricate as a single crystal, which limits practical applications to the material’s polycrystalline form; that is, a solid mixture of small crystalline particles. Even the most sophisticated lab techniques have produced crystals no larger than a quarter-inch across. A number of new applications in sensing, imaging and energy storage appear possible if the material can be fabricated in a variety of sizes and shapes with the highly ordered atomic structure of crystals.
The Rutgers-led team created PZT particles using chemical processes, forming cubes of uniform shape and size, between two and three microns on a side. The team then made a slurry of PZT cubes in an alcohol and mineral oil mixture and placed droplets of the slurry on a water surface. Various forces, including the water’s surface tension, caused the cubes to “self-assemble” into a densely packed single layer. The scientists then picked up the array of cubes onto a glass tube or microscope slide, resulting in a thin layer of crystal-like PZT.
Using atomic force microscopy, the scientists measured piezoelectric properties, or the ability to generate electricity by causing vibrations, in the PZT array. They found it had properties comparable to that of a true single-crystal structure. While additional work will be needed to make the fabrication process practical for large-scale production, the research suggests it will be possible to make materials with unique shapes and properties.