Electrons observed

Researchers at the EPFL (Ecole Polytechnique Federale de Lausanne) have developed a new machine that can reveal how electrons behave inside a single nano-object. The results from initial tests on pyramidal gallium-arsenide quantum dots are presented in an article in the November 24 issue of Nature.

The machine in EPFL’s Laboratory of quantum optoelectronics took four years to perfect and represents an equipment investment of more than a million Swiss francs.

Contemporary methods used to explore material properties and dynamics run into limits when applied at the nanoscale. Current techniques either have good spatial resolution (down to tens of nanometres or below) or an ultrafast time resolution (down to picoseconds), but not both.

The machine developed by Professor Benoit Deveaud-Pledran and his EPFL colleagues is the first tool that can track the passage of an electron in a nanostructure, at a time scale of ten picoseconds and a spatial resolution of 50 nanometres.

The EPFL researchers replaced the standard electron gun filament on an off-the-shelf electron microscope with a 20 nanometre-thick gold photocathode.

The gold is illuminated by an ultraviolet mode-locked laser, generating an electron beam that pulses 80 million times per second. Each pulse contains fewer than 10 electrons. The electrons excite the sample, causing it to emit light. The spectroscopic information is collected and analysed to recreate the surface morphology and to trace the path the electrons follow through the sample.

Deveaud-Pledran and his colleagues tested their new machine on pyramidal quantum dots. These two micron-high nano-objects, specially synthesised in the lab of EPFL professor Eli Kapon, contain several different nanostructures, making them ideal test objects. When the electron beam impacts the pyramid, the electrons diffuse towards the closest nanostructure. From there, the diffusion continues until the point of lowest energy is reached: the quantum dot at the tip of the pyramid. The time traces corresponding to each of these nanostructures reveal just how critical that 10- picosecond time resolution is; with even a 100-picosecond resolution, important information would be lost.

According to EPFL, the machine will work on any semiconductor, allowing researchers to study previously intractable materials. The wide energy range of the electrons in the beam can excite materials that won’t luminesce with laser techniques, explained Deveaud-Pledran. “With a laser, you can’t get a short enough wavelength to excite diamond or silicon, for example. This machine will.”

Nanotechnology is widely heralded as the key to the technology of the future as everything from quantum computing; ultra-dense data storage and quantum cryptography depends on the behaviour and control of materials at the nanoscale.