Ammonia goes green in carbon-free energy demonstrator

Ammonia could be used to store renewable energy, and as a source of hydrogen for fuel cell-powered vehicles, thanks to a demonstrator developed by Siemens.

ammonia

The Green Ammonia Energy Storage Demonstrator, developed by Siemens alongside the Science and Technology Facilities Council and the Universities of Oxford and Cardiff, with funding from Innovate UK, is designed to show the complete cycle of renewable power, storage as ammonia, and conversion back to electricity.

Powered by renewable energy, the device first extracts nitrogen from the air and uses electrolysis to separate hydrogen from water, according to Ian Wilkinson, programme manager at Siemens Corporate Technologies.

The two elements are then combined using the Haber-Bosch process, in which hydrogen and nitrogen are reacted under high temperature and pressure in the presence of a catalyst, to produce ammonia.

“We already know how to synthesise ammonia in big quantities, store it, and transport it; the infrastructure is already there,” said Wilkinson.

However, existing techniques to produce ammonia typically rely on the use of natural gas or other fossil fuels, meaning they generate large amounts of carbon dioxide.

The new technique could be used as a means to store excess electricity produced by intermittent renewable energy sources, for use at times when the sun is not shining or the wind is not blowing.

Ammonia could then be burnt as a fuel in gas turbines, where it emits nitrogen and water, but no CO2. “It is chemical energy storage, but it is carbon-free,” he said.

Any NOx in the exhaust gas can be removed by existing catalytic reduction processes.

The fuel can be easily transported, and can also be “cracked” back to nitrogen and hydrogen for use in fuel cells. “Ammonia is a practical and carbon-free hydrogen carrier,” said Wilkinson.

The technique could also be used to produce ammonia for fertiliser, potentially reducing worldwide CO2 emissions by 360 million tons each year.

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