Graphene-ceramic metamaterial shows promise in sensors and heat shields

Graphene-ceramic metamaterial exhibits unique properties for multiple applications

A new lightweight, flame-resistant and super-elastic metamaterial combines high strength with electrical conductivity and thermal insulation for applications ranging from heat shields to sensors.

Graphene-ceramic metamaterial (Purdue University photo)
Graphene-ceramic metamaterial (Purdue University photo)

Developed at Purdue University, the composite combines nanolayers of aluminium oxide with graphene, both of which are brittle. This attribute is countered by the metamaterial’s honeycomb microstructure, which provides super-elasticity and structural integrity.

Graphene would ordinarily degrade when exposed to high temperature, but the ceramic aluminium oxide imparts high heat tolerance and flame-resistance, properties that might be useful as a heat shield for aircraft.

The lightweight, high-strength and shock-absorbing properties could make the composite a good substrate material for flexible electronic devices and large strain sensors.

Because it has high electrical conductivity and yet is an excellent thermal insulator, it might be used as a flame-retardant, thermally insulating coating, as well as for sensors and devices that convert heat into electricity, said Gary Cheng, an associate professor in the School of Industrial Engineering at Purdue University.

“This material is lighter than a feather,” he said in a statement. “The density is really low. It has a very high strength-to-weight ratio.”

Findings have been published in Advanced Materials. The paper was a collaboration between Purdue, Lanzhou University and the Harbin Institute of Technology, both in China, and the US Air Force Research Laboratory.

A research highlight about the work appeared in Nature Research Materials.

“The outstanding properties of today’s ceramic-based components have been used to enable many multifunctional applications, including thermal protective skins, intelligent sensors, electromagnetic wave absorption and anticorrosion coatings,” Cheng said.

However, ceramic-based materials have several fundamental bottlenecks that prevent their ubiquitous use as functional or structural elements.

“Here, we report a multifunctional ceramic-graphene metamaterial with microstructure-derived super-elasticity and structural robustness,” Cheng said. “We achieved this by designing a hierarchical honeycomb microstructure assembled with multi-nanolayer cellular walls serving as basic elastic units. This metamaterial demonstrates a sequence of multifunctional properties simultaneously that have not been reported for ceramics and ceramics–matrix–composite structures.”

The composite material is made of interconnected cells of graphene sandwiched between ceramic layers. The graphene scaffold – or graphene aerogel - is chemically bonded with ceramic layers using atomic layer deposition.

“We carefully control the geometry of this graphene aerogel,” he said. “And then we deposit very thin layers of the ceramic. The mechanical property of this aerogel is multifunctional, which is very important. This work has the potential of making graphene a more functional material.”

The process might be scaled up for industrial manufacturing, he said.