Heat insulation potential of metallic composites confirmed

The finding from North Carolina State University researchers means the CMF is especially promising for use in storing and transporting nuclear material, hazardous materials, explosives and other heat-sensitive materials, as well as for space exploration.

"The presence of air pockets inside CMF make it so effective at blocking heat, mainly because heat travels more slowly through air than through metal," said Afsaneh Rabiei, a professor of mechanical and aerospace engineering at NC State and corresponding author of a paper on the work published in the International Journal of Thermal Sciences.

According to NC State, the composite metal foam consists of metallic hollow spheres - made of materials including carbon steel, stainless steel or titanium - embedded in a metallic matrix made of steel, aluminium or metallic alloys.

"We have developed two technologies for manufacturing CMFs," Rabiei said. "One is based on casting a low melting point matrix material, such as aluminium, around hollow spheres made of a material with a higher melting point, such as steel. This creates aluminium-steel CMFs, for example. The other technique is based on sintering…the matrix powder around prefabricated hollow spheres. This creates CMFs such as steel-steel, which consist of steel hollow spheres in a steel matrix."

In one test, researchers exposed samples of 2.5” by 2.5” steel-steel CMF that were 0.75” thick to a fire with an average flame temperature of 800 degrees Celsius for a period of 30 minutes on one side, and monitored the material to see how long it would take for the heat to reach the opposite side of the sample. For a piece of bulk stainless steel with the same dimensions as the CMF sample, it took four minutes to reach 800 degrees Celsius through the entire thickness of the sample. But it took eight minutes for the steel-steel CMF to reach the same temperature.

"We already knew the CMFs are light-weight materials with outstanding high-velocity impact resistance, and effective radiation shielding, now we know that it can withstand high heat," Rabiei said. "This difference in thermal conductivity means that the use of composite metal foams could help avoid circumstances where accidents can lead to explosions."

The researchers also found that the composite metal foam made entirely of stainless steel expands 80 per cent less than bulk stainless steel at 200 degrees Celsius - and the differential increases at higher temperatures.

NC State said another noteworthy advantage is that the composite metal foam expands at a fairly constant rate when exposed to high heat, whereas conventional bulk metals and alloys such as stainless steel expand more rapidly as temperature increases.

"Our findings suggest that CMF can offer extremely good thermal insulation, superior thermal stability, and excellent flame retardant performances as compared to commercially available materials such as stainless steel," Rabiei said.