Multiphoton polymerisation creates 3D printed glass objects

Researchers have developed a laser-based process for 3D printing parts made of glass, an advance that could lead to complex optics for vision or laser-based applications. 

Multiphoton polymerisation
Researchers have developed a new laser-based process for 3D printing intricate parts made of glass using multiphoton polymerisation to create the object directly in a 3D volume (Image: Laurent Gallais, The Fresnel Institute and Ecole Centrale Marseille)

According to research team leader Laurent Gallais from The Fresnel Institute and Ecole Centrale Marseille in France, the new process avoids the limitations of building an object in layers by using a laser beam to polymerise a liquid precursor into solid glass.

3D printing has potential to cut cost of optical silica fibres

In The Optical Society (OSA) journal Optics Letters, Gallais and research team members Thomas Doualle and Jean-Claude Andre demonstrate how they used the new technique to create a variety of silica glass objects such as miniature models of a bike and the Eiffel Tower without any pores or cracks.

The 3D printing approach is based on multiphoton polymerisation, which ensures that polymerisation takes place at the precise laser focal point. It allows direct fabrication of 3D parts that range in size from a few microns to tens of centimetres with a resolution that is theoretically only limited by the optics used for laser beam shaping.

"Glass is one of the primary materials used to make optics," Gallais said in a statement. "Our work represents a first step toward developing a process that could one day allow scientists to 3D print the optical components they need."

Using a traditional layer-by-layer approach to build 3D glass objects comes with several limitations. The speed of the printing process is limited by the time it takes to build the layers, and it can be difficult to create layers with consistent thicknesses when using highly viscous resins. Making complex parts typically requires supports, which must be precisely positioned and then removed once the object hardens.

Although multiphoton polymerisation can be used to avoid the layer-by-layer approach, 3D printing glass objects requires a material that is transparent at the wavelength of the laser during the initial liquid phase and once polymerised. It must also absorb the laser light at half the laser wavelength to initiate the multiphoton polymerisation process.

To accomplish this, the researchers are said to have used a mixture containing a photochemical initiator to absorb the laser light, a resin and high concentration of silica nanoparticles. In addition to working well with the laser, this mixture's high viscosity allows a 3D part to be formed without deformation problems or supports to keep the object in place during 3D printing.

"Critical to the technique were high power ultrashort lasers based on Strickland and Mourou's chirped pulse amplification technology," said Gallais. "Only intense and very short pulses will create non-linear photo polymerisation with high precision and no thermal effects."

After validating that a solid object could be created using the silica nanoparticle mixtures, the researchers used their 3D printing approach to create objects with complex shapes. They also applied a process that transforms the polymerised parts into glass.

"Our approach could potentially be used to produce almost any type of 3D glass object," said Gallais. "For example, we are exploring the possibility of producing glass parts that could be used on luxury watches or perfume bottles."

The researchers are working to make the technique more practical and reduce cost by experimenting with less expensive laser sources. They also want to optimise the process to improve the surface quality to decrease roughness.