Metal oxides play a crucial role in processes that reduce CO2 emissions, including carbon capture, utilisation and storage (CCUS), purifying and recycling inert gases in solar panel manufacturing, thermochemical energy storage, and producing hydrogen.
These processes are based on redox reactions, but the performance of metal oxides suffers under redox reactions at the high temperatures required for chemical manufacturing.
Now, a team led by Imperial College London has developed a new materials design strategy that produces copper-based metal oxides that are said to perform better under high temperatures. The team’s research is published in Nature Communications.
In a statement, senior author Dr Qilei Song, of Imperial’s Department of Chemical Engineering, said: “As the world transitions to net zero, we need more innovative industrial processes for decarbonisation. To enhance energy security, we must diversify the electricity supply, from renewable energy generation and storage to clean use of fossil fuels with CCUS technologies. Our improved metal oxides hold great potential for use in the energy processes that are helping us reach net zero.”
Metal oxides are essential in the chemical looping combustion (CLC) process, which is an alternative way of burning fossil fuels that uses metal oxides, such as copper oxides, to transport oxygen from the air to react with the fuel. The reaction produces CO2 and steam, which is condensed to allow the capture of CO2.
A key issue that has held back CLC from use on a larger scale is metal oxides’ inability to maintain good oxygen-releasing performance over multiple redox cycles at high temperatures.
To solve the problem, the researchers examined the fundamental structures of the metal oxides used in CLC, reasoning that the precursor chemistry to metal oxides was poorly understood.
Co-lead author Michael High, PhD candidate at Imperial’s Department of Chemical Engineering, said: “To solve the question of how metal oxides maintain their performance, we looked to the basics of the chemical processes involved in CLC. This is a key example of combining fundamental research and smart design to produce a strategy that’s applicable to a wide range of engineering processes.”
They used an alternative way to engineer the metal oxide structure from a well-known precursor composed of copper-magnesium-aluminium layered double hydroxides (LDHs). By tailoring the chemistry of LDH precursors, researchers found they could produce metal oxides that could still perform well under high temperatures. They demonstrated this by putting the oxides through 100 chemical cycles in a fluidised bed reactor for 65 hours.
Their greater ability to withstand heat means that metal oxides produced this way can be used to unleash more power from purifying and recycling inert gases like argon in manufacturing solar panels, capturing and storing carbon, chemical energy storage, and producing hydrogen. To show this, the researchers scaled up the production of metal oxides for use in fluidised bed reactors and found that creating these materials is simple and readily suitable for upscaling using existing industrial manufacturing methods.
The researchers will next study the long-term stability of the materials during the combustion of different types of fuels, explore new applications for thermochemical energy storage, and extend the approach to other metal oxide systems for producing clean hydrogen via thermochemical redox cycles.
This research was funded by EPSRC, European Research Council, China Scholarship Council, and the National Science Foundation for Distinguished Young Scholars of China.
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