New 3D printing method is sustainable and reversible

Engineers at the University of California San Diego have developed a new 3D printing method that uses a polymer ink and salt water solution to create solid structures.

A structure created using a simple, eco-friendly 3D printing method developed by UC San Diego engineers
A structure created using a simple, eco-friendly 3D printing method developed by UC San Diego engineers - Credit: Donghwan Ji

Detailed in Nature Communications, the work is claimed to have the potential to make materials manufacturing more sustainable and environmentally friendly.

The process uses PNIPAM (poly(N-isopropylacrylamide)) ink. When this PNIPAM ink is extruded through a needle into a calcium chloride salt solution, it instantly solidifies as it contacts the salt water.

This rapid solidification is driven by the salting-out effect, where the salt ions draw water molecules out of the polymer solution due to their strong attraction to water. This removal of water causes the hydrophobic polymer chains in the PNIPAM ink to densely aggregate, creating a solid form.

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In a statement, senior author Jinhye Bae said: “This is all done under ambient conditions, with no need for additional steps, specialised equipment, toxic chemicals, heat or pressure.”

Traditional methods for solidifying polymers typically require energy-intensive steps and harsh substances. In contrast, this new process harnesses the interaction between PNIPAM and salt water at room temperature to achieve the same result, but without the environmental cost.

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